Calcium hydroxide, sodium hydroxide, and ammonium hydroxide are most often responsible for alkali burns. Eur., 25-30% NH 3 basis, 5. Ammonium hydroxide penetrates most rapidly of all alkali compounds. /Conditions of bioassay not specified, Toxicity to daphnia and other aquatic invertebrates: LC50 Daphnia magna 0.66 mg/l/48 hr 22\u00b0C /Conditions of bioassay not specified, Toxicity to microorganisms: no data available, ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road, RID: Regulation concerning the International Carriage of Dangerous Goods by Rail, IMDG: International Maritime Dangerous Goods, IATA: International Air Transportation Association, IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home, HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/, eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en, CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple, ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp, ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg, Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp, ECHA - European Chemicals Agency, website: https://echa.europa.eu/. Artificial respiration may be needed. Consult an expert! P321 Specific treatment (see ... on this label). Contact with molten substance may cause severe burns to skin and eyes. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. Safety glasses with side-shields conforming to EN166. Stable under recommended storage conditions. Wear self-contained breathing apparatus for firefighting if necessary. Product Identification Synonyms: Ammonium hydroxide solutions; ammonia aqueous; ammonia solutions CAS No. If breathing is difficult, give oxygen. 4 0 obj Do not get water inside containers. Avoid breathing vapours, mist or gas. Ammonium hydroxide reacts with many heavy metals and their salts forming explosive compounds. For personal protection see section 8. PRODUCT AND COMPANY IDENTIFICATION Product name: Ammonium Hydroxide ~30% Product code: 05870-16 Supplier: StatLab Medical Products 2090 Commerce Drive McKinney, TX 75069 800-442-3573 972-436-1369 Fax statlab.com Synonym: None. Refer for medical attention . If not breathing, give artificial respiration. Keep in a well-ventilated room. Move containers from fire area if you can do it without risk. Revised on 04/26/2016 Page 1 of 6 Safety Data Sheet Ammonium Hydroxide 29%, CMOS 1. Consult the regulatory requirements of the US Department of Transportation before shipping. P260 Do not breathe dust/fume/gas/mist/vapours/spray. plus, ≥25% NH 3 in H 2 O, 05003 Ammonium hydroxide solution, puriss., meets analytical specification of Ph. First Aid Procedures: Inhalation: Move to fresh air. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Aqua Ammonia 19% Wash and dry hands. Rinse skin with plenty of water or shower. CAUSTIC LIQ FORMS EXPLOSIVE CMPD WITH MANY HEAVY METALS SUCH AS SILVER, LEAD, ZINC, & THEIR SALTS, ESPECIALLY HALIDE SALTS. Aqueous ammonia and Hg react to form an explosive solid, likely a fulminate. LARGE FIRE: Dry chemical, CO2, alcohol-resistant foam or water spray. Injuries are caused by neutral organic, acid, and alkali compounds. Do NOT let this chemical enter the environment. p.a. The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Alkali compounds cause most severe injuries depending on the hydroxyl ion concentration and the cation. P363 Wash contaminated clothing before reuse. Remove contact lenses, if present and easy to do. Remove contaminated clothes. PRODUCT AND COMPANY IDENTIFICATION Product Name: Ammonium Hydroxide 29%, CMOS Synonyms/Generic Names: Aqueous ammonia, Ammonia solution Product Number: 0486 Product Use: Industrial, Manufacturing or Laboratory use Manufacturer: Columbus Chemical Industries, Inc. Such a precipitate can explode on stirring [MCA Case History 1554 1968]. Handle in accordance with good industrial hygiene and safety practice. Tai`an Ming Chen Chemical Import&Export Co.,Ltd. Rinse mouth. Refer for medical attention . Give one or two glasses of water to drink. Separated from food and feedstuffs. Do not discharge to sewer systems. J., 1964, 10, 274.). Engrs. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. What is Ammonium hydroxide. IDENTIFICATION Product name Ammonium Hydroxide Solution 24.5% Common name Ammonium Hydroxide NH4OH Chemical type Strong base Recommended restrictions Use in accordance with supplier’s recommendations Company Name CALAMCO 1776 W. March Lane Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Reacts extremely violently with dimethyl sulfate [NFPA 491M 1991]. Agents causing ocular burns, steps in treatment, and special problems are described. WARNING! Personal protection: complete protective clothing including self-contained breathing apparatus. Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. 5. Sweep up and shovel. The corneal epithelium and endothelium provide a barrier to water soluble substances while the stroma is a barrier to lipid soluble substances.
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